By default, bill me uses the Billing Address on the Account object, you can customize Nimble AMS to use another address.
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From Setup, click Customize | Accounts | Field Sets.
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Click Edit next to "Bill Me Address".
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Click and drag fields into the "In the Field Set" area.
Press CTRL/CMND to select multiple fields.
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For each field, click
Nimble AMS, Staff View, Button, Wrench, and select Required, and click OK.
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Click Save.